Adsorption and Desorption Kinetics for Diffusion Controlled Systems

نویسنده

  • Douglas M. Ruthven
چکیده

The formal solution to the diffusion equation for transient adsorption in a semiinfinite medium with a strongly concentration dependent diffusivity, originally derived by Fujita ( 3 , has been extended to desorption. Profiles for adsorption and desorption are compared and simplified asymptotic expressions which are useful when the diffusivity ratio is large are derived. The effect of a strongly concentration dependent diffusivity on adsorption and desorption kinetics is briefly considered.

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تاریخ انتشار 2007